Parahydrogen-induced polarization in alkyne hydrogenation catalyzed by Pd nanoparticles embedded in a supported ionic liquid phase.
Parahydrogen-induced polarization in alkyne hydrogenation catalyzed by Pd nanoparticles embedded in a supported ionic liquid phase.
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嵌入负载型离子液体相中的 Pd 纳米粒子催化炔烃氢化中的仲氢诱导极化。
DOI：
10.1039/c0cc01411g
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发表时间：
2010
影响因子：
4.9
通讯作者：
I. Koptyug
中科院分区：
文献类型：
--
作者：
K. Kovtunov;V. Zhivonitko;L. Kiwi;I. Koptyug
在活性炭纤维负载的离子液体相负载Pd（0）纳米粒子（Pd（0）/SILP/ACF）催化丙炔气相多相加氢反应中，观察到了仲氢诱导极化现象.结果明显不同于用参比催化剂Pd（0）/ACF获得的结果，证明了离子液体的重要作用。
Parahydrogen-induced polarization was observed in the gas phase heterogeneous hydrogenation of propyne catalyzed by Pd(0) nanoparticles embedded in an ionic liquid phase supported on activated carbon fibers (Pd(0)/SILP/ACF). The results were markedly different from those obtained with a reference catalyst, Pd(0)/ACF, demonstrating the important role of the ionic liquid.