Enantioselective total synthesis of both diastereomers of preclavulone-A methyl ester
Enantioselective total synthesis of both diastereomers of preclavulone-A methyl ester
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DOI：
10.1016/j.tet.2006.08.068
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发表时间：
2006-10-29
期刊：
影响因子：
2.1
通讯作者：
Iguchi, Kazuo
中科院分区：
文献类型：
--
作者：
Ito, Hisanaka;Momose, Tsutomu;Iguchi, Kazuo
以对映体纯的5为原料，采用立体控制的方法，实现了前锁骨酮-A甲酯及其非对映体的对映选择性全合成。通过比较[alpha]（D）值来确定天然存在的前锁骨酮-A甲酯的绝对立体化学。(c)2006年由Elsevier Ltd.出版
The enantioselective total synthesis of preclavulone-A methyl ester and its diastereomer was achieved from enantiomerically pure 5 in a stereocontrolled manner. The absolute stereochemistry of naturally occurring preclavulone-A methyl esters was determined by comparison of the [alpha](D) value. (c) 2006 Published by Elsevier Ltd.