Photochromism of Diarylethene-functionalized Polystyrene with High Conversion in a Solid-state Polymer Film

Photochromism of Diarylethene-functionalized Polystyrene with High Conversion in a Solid-state Polymer Film
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DOI:
10.1246/cl.2006.628
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发表时间:
2006-05
期刊:
影响因子:
1.6
通讯作者:
S. Kobatake;Hirotsugu Kuratani
S. Kobatake;Hirotsugu Kuratani
中科院分区:
化学4区
文献类型:
--
作者:
S. Kobatake;Hirotsugu Kuratani

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通过具有光致变色二芳基乙烯发色团的苯乙烯单体的自由基聚合,合成了表现出热不可逆和光化学可逆颜色变化的光致变色聚合物。即使在固态聚合物膜中,聚合物的光致变色反应也以高转化率进行。
Photochromic polymers that exhibit thermally irreversible and photochemically reversible color changes were synthesized by radical polymerization of a styrene monomer having a photochromic diarylethene chromophore. The photocoloration reaction of the polymer proceeded with high conversion even in the solid-state polymer film.