Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals.

Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals.
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过渡金属的镁,锌,铝和甘油氢化物络合物。

DOI:
10.1039/c6cc05702k
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发表时间:
2017-01-24
期刊:
Chemical communications (Cambridge, England)
影响因子:
--
通讯作者:
Crimmin MR
Crimmin MR
中科院分区:
其他
文献类型:
--
作者:
Butler MJ;Crimmin MR

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在这里,我们对TM-H-M键(M=镁、锌、铝、镓)的最新理解进行了综述和整理。我们讨论了这些络合物的结构和成键,它们的已知反应活性,以及它们在催化方面的大部分未实现的潜力。异双金属配合物的制备和应用一直是有机金属、主基和配位化学领域的研究热点。这种兴趣源于这些配合物作为材料的前体、合成试剂和新催化剂的前景。在这里,我们对TM-H-M键(M=镁、锌、铝、镓)的最新理解进行了综述和整理。我们讨论了这些络合物的结构和成键,它们的已知反应活性,以及它们在催化方面的大部分未实现的潜力。
Here we survey and organise the state-of-the-art understanding of the TM–H–M linkage (M = Mg, Zn, Al, Ga). We discuss the structure and bonding in these complexes, their known reactivity, and their largely unrealised potential in catalysis. The preparation and applications of heterobimetallic complexes continue to occupy researchers in the fields of organometallic, main group, and coordination chemistry. This interest stems from the promise these complexes hold as precursors to materials, reagents in synthesis and as new catalysis. Here we survey and organise the state-of-the-art understanding of the TM–H–M linkage (M = Mg, Zn, Al, Ga). We discuss the structure and bonding in these complexes, their known reactivity, and their largely unrealised potential in catalysis.
DOI: 10.1021/om049589r
发表时间: 2004-09-27
期刊: ORGANOMETALLICS
影响因子: 2.8
作者:
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发表时间: 2000-06-14
影响因子: 15
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