REACTIONS OF (CO)5WC(TOL)2 WITH ALKENES - MODEL FOR STRUCTURAL SELECTIVITY IN OLEFIN METATHESIS REACTION
REACTIONS OF (CO)5WC(TOL)2 WITH ALKENES - MODEL FOR STRUCTURAL SELECTIVITY IN OLEFIN METATHESIS REACTION
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DOI：
10.1021/ja00418a049
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发表时间：
1976-01-01
影响因子：
15
通讯作者：
SAEMAN, MC
中科院分区：
文献类型：
--
作者：
CASEY, CP;TUINSTRA, HE;SAEMAN, MC
烯烃歧化反应具有明显的结构选择性。1相对复分解速率按以下顺序递减：(1)端烯亚甲基团的简并交换；(2)端烯与内烯的交叉复分解；(3)端烯与内烯的复分解。
The olefin metathesis reaction shows a pronounced struc-tural selectivity. 1 The relative rates of metathesis decrease in the order:(1) the degenerate exchange of methylene units between terminal alkenes6-7>(2) cross metathesis of terminal and internal alkenes3-8-9>(3) metathesis of inter-