Multiple C-H borylation of phenylhydrazones to boron-nitrogen analogues of benzopentalene.
Multiple C-H borylation of phenylhydrazones to boron-nitrogen analogues of benzopentalene.
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DOI:
10.1039/c5cc00471c
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发表时间:
2015-03
影响因子:
4.9
通讯作者:
Cong Ma;Jianying Zhang;Jianfeng Li;C. Cui
中科院分区:
文献类型:
--
作者:
Cong Ma;Jianying Zhang;Jianfeng Li;C. Cui
One-pot multiple borylation of phenylhydrazones to a series of novel boron-nitrogen analogues of benzopentalene by the cleavage of C-H bonds with PhBBr2 mediated by NEt3 has been established. The resulting BN benzopentalenes feature unique electronic structures and are luminescent both in solution and the solid state.