Structure of subcritical and supercritical hydrogen-bonded liquids and solutions
Structure of subcritical and supercritical hydrogen-bonded liquids and solutions
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DOI：
10.1016/s0167-7322(98)00083-x
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发表时间：
1998-08-01
影响因子：
6
通讯作者：
Yamaguchi, T
中科院分区：
文献类型：
--
作者：
Yamaguchi, T
通过使用二维成像板探测器的快速溶液 X 射线衍射和使用同位素取代技术的中子衍射，在原子尺度上确定了亚临界和超临界水、甲醇和氯化锂水溶液的结构。简要描述了过去十年在液体和溶液结构测定方面取得的突破。结合超临界流体的物理化学性质和化学反应，讨论了亚临界和超临界液体和溶液中的氢键、离子水合和离子缔合。 (C) 1998 Elsevier Science B.V. 保留所有权利。
The structures of subcritical and supercritical water, methanol, and aqueous lithium chloride solutions have been determined on an atomic scale by rapid solution X-ray diffraction with a two-dimensional imaging plate detector and neutron diffraction with isotopic substition techniques. The breakthroughs made in the last decade in structure determination of liquids and solutions are briefly described. The hydrogen bonding, ionic hydration, and ion association in the subcritical and supercritical liquids and solutions are discussed in connection with the physico-chemical properties and chemical reactions in supercritical fluids. (C) 1998 Elsevier Science B.V. All rights reserved.