A titanium salicylate, Na4[Ti(C7H4O3)3]2•11H2O
A titanium salicylate, Na4[Ti(C7H4O3)3]2•11H2O
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DOI：
10.1107/s1600536805021276
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发表时间：
2005-08-01
期刊：
影响因子：
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通讯作者：
Roychowdhury, P
中科院分区：
文献类型：
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作者：
Dey, R;Mukharjee, K;Roychowdhury, P
标题化合物为十一水合四水杨酸双[三水杨酸钛酸酯（IV）]，Na-4[Ti（C7 H4 O3）（3）]（2）中心点11 H（2）O，在不对称单元中含有2个水杨酸钛络离子、4个钠离子和11个水分子。一个水O原子在两个位置上是无序的，具有0.74（5）和0.26（5）的占有率。钛原子和三个钠离子均采用O原子畸变的八面体配位。第四个钠离子具有扭曲的三角双锥氧配位，与钠配位八面体共享一个边缘。
The title compound, tetrasodium bis[tris(salicylatotitanate(IV)] undecahydrate, Na-4[Ti(C7H4O3)(3)](2)center dot 11H(2)O, crystallizes with two titanium salicylate complex ions, four sodium ions and 11 water molecules in the asymmetric unit. One water O atom is disordered over two positions, having 0.74 ( 5) and 0.26 ( 5) occupancy. Both Ti atoms and three sodium ions adopt a distorted octahedral coordination by O atoms. The fourth sodium ion has a distorted trigonal-bipyramidal coordination by oxygen, sharing one edge with a sodium coordination octahedron.