Ionothermal synthesis-ionic liquids as functional solvents in the preparation of crystalline materials
Ionothermal synthesis-ionic liquids as functional solvents in the preparation of crystalline materials
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DOI：
10.1039/b902611h
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发表时间：
2009-01-01
影响因子：
4.9
通讯作者：
Morris, Russell E.
中科院分区：
文献类型：
--
作者：
Morris, Russell E.
离子液体合成是在固体形成中同时使用离子液体作为溶剂和潜在的模板或结构导向剂。它直接平行于溶剂为水的水热合成。在这篇专题文章中，我讨论了离子合成的一般特征，以及这种合成的性质与其他合成方法的性质有何不同。特别是，我将讨论离子液体阴离子在确定合成固体的结构中的作用，矿化剂如水和氟化物的作用，以及有针对性地使用不稳定的离子液体来生产新的无机和无机-有机杂化材料。
Ionothermal synthesis is the use of ionic liquids simultaneously as both the solvent and potential template or structure directing agent in the formation of solids. It directly parallels hydrothermal synthesis where the solvent is water. In this feature article I discuss the general features of ionothermal synthesis and how the properties of the synthesis differ from those of other synthetic methodologies. In particular, I will discuss the role of the ionic liquid anion in determining the structure of the synthesised solid, the role of mineralisers such as water and fluoride, and the targeted use of unstable ionic liquids to produce new inorganic and inorganic-organic hybrid materials.