$sup 60$Co $gamma$ RADIOLYSIS OF SOLUTIONS OF POTASSIUM BROMIDE IN 0.8 N SULFURIC ACID.

$sup 60$Co $gamma$ RADIOLYSIS OF SOLUTIONS OF POTASSIUM BROMIDE IN 0.8 N SULFURIC ACID.
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$sup 60$Co $gamma$ 0.8 N 硫酸中溴化钾溶液的辐射分解。

DOI:
10.1021/j100862a022
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发表时间:
1967
期刊:
The Journal of Physical Chemistry
影响因子:
--
通讯作者:
Farhataziz
Farhataziz
中科院分区:
--
文献类型:
--
作者:
Farhataziz

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结果脱气溶液。测得的100-ev产率用G表示,初级产率用g表示。所有溶液均在0.8NH2SO4中。产生的氧气的G= 0.008,在溴化物浓度范围3 × 10-5至3 × 10-3 M和剂量高达450 × 1020 ev l时是恒定的。- -一.对于相同的剂量范围和溴化物浓度范围1 × 10-6至3 × 10-3 M,(t(H2 O2 + Br 2)=0.38,其中Br 2包括Br 3-。在3 × 10~(-5)M KBr溶液中,为KBr的分析提供了最佳条件,G为消失-
ResultsDeaerated Solutions. Measured 100-ev yields are denoted by G and primary yields by g. All solutions were in 0.8 Nh2sc> 4. Oxygen is produced with a G= 0.008 that is constant over the bromide concentration range 3 X 10-5 to 3 X 10-3 M and for doses up to 450 X 1020 ev l. _I. For the same dose range and for the bromide concentration range 1 X 10-6 to 3 X 10-3 M,(t (H202+ Br2)=0.38, where Br2 includes Br3~. In 3 X 10~ 5 M KBr solutions, which provided the best conditions for KBr analysis, G for thedisappear-