Star polymers with POSS via azide–alkyne click reaction
Star polymers with POSS via azide–alkyne click reaction
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DOI：
10.1002/pola.23637
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发表时间：
2009-11
期刊：
影响因子：
--
通讯作者：
E. Gungor;Cigdem Bilir;H. Durmaz;G. Hizal;Umit Tunca
中科院分区：
文献类型：
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作者：
E. Gungor;Cigdem Bilir;H. Durmaz;G. Hizal;Umit Tunca
叠氮基丙基七异丁基取代的多面体低聚倍半硅氧烷（POSS-N3）与1，1，1-三[4-]反应（2-丙炔氧基）苯基]-乙烷（1）和聚聚乙二醇-b-聚中心含炔的聚甲基丙烯酸甲酯共聚物（PEG-PMMA-炔）分别首次合成了3-臂星星型POSS和PEG-PMMA-POSS 3-杂臂星星型POSS，以CuBr/N，N，N′，N″，N″-五甲基二亚乙基三胺为催化剂，N，N-二甲基甲酰胺/四氢呋喃为溶剂，在室温下反应。采用1H NMR、GPC和DSC对前驱体和目标星星聚合物进行了表征。© 2009威利期刊公司.聚合物科学杂志A部分：聚合物化学47：5947-5953，2009
Azidopropyl-heptaisobutyl-substituted polyhedral oligomeric silsesquioxane (POSS-N3) was reacted with 1,1,1-tris[4-(2-propynyloxy)phenyl]-ethane (1) and poly(ethylene glycol) (PEG)-b-poly(methyl methacrylate) (PMMA) copolymer with alkyne at its center (PEG-PMMA-alkyne) affording the first time synthesis of 3-arm star POSS and PEG-PMMA-POSS 3-miktoarm star terpolymer, respectively, in the presence of CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine as catalyst and N,N-dimethylformamide/tetrahydrofuran as solvent at room temperature. The precursors and the target star polymers were characterized comprehensively by 1H NMR, GPC, and DSC. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5947–5953, 2009