Design and characterization of novel dirhodium coordination polymers – the impact of ligand size on selectivity in asymmetric cyclopropanation

Design and characterization of novel dirhodium coordination polymers – the impact of ligand size on selectivity in asymmetric cyclopropanation
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DOI:
10.1039/d1cy00109d
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发表时间:
2021
影响因子:
5
通讯作者:
Zhenzhong Li;Lorenz Rösler;T. Wissel;H. Breitzke;K. Hofmann;H. Limbach;T. Gutmann;G. Buntkowsky
Zhenzhong Li;Lorenz Rösler;T. Wissel;H. Breitzke;K. Hofmann;H. Limbach;T. Gutmann;G. Buntkowsky
中科院分区:
化学2区
文献类型:
--
作者:
Zhenzhong Li;Lorenz Rösler;T. Wissel;H. Breitzke;K. Hofmann;H. Limbach;T. Gutmann;G. Buntkowsky

文献摘要

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合成了一种新型的配位聚合物,并用多种光谱技术对其进行了表征。该催化剂在重氮氧吲哚的环丙烷化反应中表现出良好的稳定性和良好的催化性能和选择性。
Novel dirhodium coordination polymers are synthesized and characterized by various spectroscopic techniques. The catalysts exhibit good stability and excellent catalytic performance and selectivity in the cyclopropanation of diazooxindoles.