Facile synthesis of diiodinated dihydronaphthalenes and naphthalenes via iodine mediated electrophilic cyclization.

Facile synthesis of diiodinated dihydronaphthalenes and naphthalenes via iodine mediated electrophilic cyclization.
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DOI:
10.1039/c0cc05442a
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发表时间:
2011-03
影响因子:
4.9
通讯作者:
F. Yang;T. Jin;M. Bao;Yoshinori Yamamoto
F. Yang;T. Jin;M. Bao;Yoshinori Yamamoto
中科院分区:
化学2区
文献类型:
--
作者:
F. Yang;T. Jin;M. Bao;Yoshinori Yamamoto

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通过各种芳基炔丙醇的亲电碘环化反应,发展了一种简便、有效、通用的合成2,3-二碘化1,4-二氢噻吩和萘的方法。所得产物2 p可用于合成红荧烯中间体。
A facile, efficient, and general synthetic method for a wide range of 2,3-diiodinated 1,4-dihydrothiophenes and naphthalenes has been developed via the electrophilic iodocyclization of various aryl propargyl alcohols. The resulting product 2p can be used for the synthesis of a rubrene intermediate.