Thermodynamic and kinetic studies of migratory carbon monoxide insertion in alkyl complexes of iron(II)
Thermodynamic and kinetic studies of migratory carbon monoxide insertion in alkyl complexes of iron(II)
复制标题
铁(II)烷基配合物中迁移一氧化碳插入的热力学和动力学研究
DOI：
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发表时间：
1993
期刊：
影响因子：
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通讯作者：
G. Reichenbach
中科院分区：
文献类型：
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作者：
G. Bellachioma;G. Cardaci;C. Jablonski;A. Macchioni;G. Reichenbach
本文研究了在甲苯中，顺，反-Fe（CO）_2（PMe_3）_2MeX与一氧化碳反应生成相应的顺，反-和反，反-乙酰基的反应，当XCl>Br>I时，反应的平衡常数由X的吸光度决定，而反，反-乙酰基与顺，反-乙酰基的反应平衡常数则由大到小的顺序为I>Br>Cl>>CN。
The reaction of cis,trans-Fe(CO) 2 (PMe 3 ) 2 MeX with carbon monoxide to give the corresponding cis,trans- and trans,trans-acetyls has been studied in toluene for X Cl>Br>I and are determined by the withdrawing power of X, while the equilibrium constants of trans,trans-acetyl as compared to cis,trans-acetyl follow the order I>Br>Cl>>CN.