Porphyrinic metal-organic frameworks from custom-designed porphyrins

Porphyrinic metal-organic frameworks from custom-designed porphyrins
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DOI:
10.1039/c5ce02106e
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发表时间:
2016-01-01
期刊:
影响因子:
3.1
通讯作者:
Kim, Youngmee
Kim, Youngmee
中科院分区:
化学3区
文献类型:
--
作者:
Huh, Seong;Kim, Sung-Jin;Kim, Youngmee

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本文重点介绍了卟啉金属有机框架(porph-MOFs)组装金属离子和定制设计的卟啉。根据卟啉-MOFs中多位卟啉桥连配体的类型,将内容分为三个部分:(1)含有5,10,15,20-四的卟啉-MOFs(4-吡啶基)卟啉(TPyP)配体和其他基于吡啶基的卟啉桥连配体,(2)含有5,10,15,20-四(4-吡啶基)卟啉的卟啉-MOFs,(4-羧基苯基)卟啉(TCPP)配体和其它基于羧基苯基的卟啉桥连配体,和(3)含有其它定制设计的基于卟啉的桥连配体的卟啉-MOFs。
This paper highlights porphyrinic metal-organic frameworks (porph-MOFs) assembled from metal ions and custom-designed porphyrins. The contents are divided into three sections based on the types of polytopic porphyrin bridging ligands in porph-MOFs: (1) porph-MOFs containing 5,10,15,20-tetra(4-pyridyl)porphyrinato (TPyP) ligand and other pyridyl-based porphyrin bridging ligands, (2) porph-MOFs containing 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinato (TCPP) ligand and other carboxyphenyl-based porphyrin bridging ligands, and (3) porph-MOFs containing other custom-designed porphyrin-based bridging ligands.