Application of μ-Nitrido- and μ-Carbido-Bridged Iron Phthalocyanine Dimers as Cathode-Active Materials for Rechargeable Batteries

Application of μ-Nitrido- and μ-Carbido-Bridged Iron Phthalocyanine Dimers as Cathode-Active Materials for Rechargeable Batteries
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DOI:
10.1021/acsami.1c10540
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发表时间:
2021-08-20
影响因子:
9.5
通讯作者:
Yoshikawa, Hirofumi
Yoshikawa, Hirofumi
中科院分区:
材料科学2区
文献类型:
--
作者:
Shimizu, Takeshi;Wakamatsu, Katsuhiro;Yoshikawa, Hirofumi

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mu-Nitrido- and mu-carbido-bridged iron phthalocyanine dimers, when used as cathode-active materials for rechargeable lithium batteries, showed four stable redox waves in cyclic voltammetry studies in solution and a stable discharge capacity of approximately 60 mAh g(-1) after 200 cycles. These results indicate that mu-heteroatom-bridged iron phthalocyanine dimers are good platforms for designing novel phthalocyanine-based electrode-active materials.