Effect of Atmospheric Pressure Plasma Treatment on the Lap-Shear Strength of Adhesive-Bonded Sheet Molding Compound Joints

Effect of Atmospheric Pressure Plasma Treatment on the Lap-Shear Strength of Adhesive-Bonded Sheet Molding Compound Joints
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大气压等离子体处理对胶粘片状模塑料接头搭接剪切强度的影响

DOI:
10.1007/s42154-018-0027-7
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发表时间:
2018-07
影响因子:
6.1
通讯作者:
Shanglu Yang
Shanglu Yang
中科院分区:
工程技术4区
文献类型:
--
作者:
Shuang Wang;Junying Min;Jianping Lin;Chengcheng Sun;Shanglu Yang

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采用常压等离子体处理(APPT)技术对SMC基材进行处理,以提高SMC粘接接头的搭接剪切强度。此外,本文还探讨了appt处理的胶粘剂粘合SMC接头的搭接剪切强度提高的机制。当APPT距离设置为20 mm时,最大搭剪强度约为接收SMC节点的3倍。表面粗糙度对搭接抗剪强度影响不大,并不是导致搭接抗剪强度增加的主要原因。具体而言,x射线光电子能谱显示,APPT后含O基团(即C-O-H、C-O-C、H-O-C =O或R-O-C =O)的增加有助于提高搭剪强度。此外,APPT后表面自由能显著增加,提高了胶粘剂粘合SMC接头的搭接剪切强度。与表面形貌的变化相比,表面化学性质和表面自由能的变化对提高appt处理SMC接头的搭剪强度的作用更大。
Atmospheric pressure plasma treatment (APPT) technology was used herein to treat sheet molding compound (SMC) substrates to increase the lap-shear strength of adhesive-bonded SMC joints. Further, the mechanisms behind the lap-shear strength improvements in APPT-treated adhesive-bonded SMC joints were explored. A maximum lap-shear strength about three times that of the as-received SMC joints was achieved when the APPT distance was set to 20 mm. The surface roughness, which exhibited little benefit to the lap-shear strength, was determined to not be the primary reason for the increase in lap-shear strength. Specifically, X-ray photoelectron spectra revealed that an increased amount of O-containing groups (i.e., C–O–H, C–O–C, H–O–C=O or R–O–C=O) following APPT contributed to the improved lap-shear strength. In addition, the surface free energy increased significantly after APPT, which improved the lap-shear strength of the adhesive-bonded SMC joints. Compared to the change of surface morphology, the changes in both the surface chemical property and surface free energy played larger roles in increasing the lap-shear strength of APPT-treated SMC joints.
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