Taming Hazardous Chemistry in Flow: The Continuous Processing of Diazo and Diazonium Compounds
Taming Hazardous Chemistry in Flow: The Continuous Processing of Diazo and Diazonium Compounds
复制标题
DOI：
10.1002/chem.201404348
复制
发表时间：
2015-02-02
影响因子：
4.3
通讯作者：
Maguire, Anita R.
中科院分区：
文献类型：
--
作者：
Deadman, Benjamin J.;Collins, Stuart G.;Maguire, Anita R.
重氮基团和重氮基团的合成用途仅与其爆炸性分解的声誉相匹配。连续加工技术为在一定范围内制造和使用这些多功能中间体提供了新的机会，并且比传统批量工艺提高了安全性。在这篇小综述中，讨论了反应性重氮和重氮物质的连续流动加工的最新技术。
The synthetic utilities of the diazo and diazonium groups are matched only by their reputation for explosive decomposition. Continuous processing technology offers new opportunities to make and use these versatile intermediates at a range of scales with improved safety over traditional batch processes. In this minireview, the state of the art in the continuous flow processing of reactive diazo and diazonium species is discussed.