Substrate participation ultrafast synthesis of amorphous NiFe nanosheets on iron foam at room temperature toward highly efficient oxygen evolution reaction

Substrate participation ultrafast synthesis of amorphous NiFe nanosheets on iron foam at room temperature toward highly efficient oxygen evolution reaction
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室温下基底参与超快合成泡沫铁上非晶态 NiFe 纳米片实现高效析氧反应

DOI:
10.1016/j.jechem.2019.03.018
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发表时间:
2019-08-01
影响因子:
13.1
通讯作者:
Chen, Yong
Chen, Yong
中科院分区:
化学1区
文献类型:
--
作者:
Yang, Xiao;Chen, Qian-Qian;Chen, Yong

文献摘要

被引文献

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地球上丰富的过渡金属基纳米材料被认为是最先进的析氧反应(OER)电催化剂。最近的研究表明,非晶材料比它们的晶体形式更活跃。在此,我们展示了一种简单快速的衬底参与方法,在室温下在泡沫铁(a-NiFe NS/IF)上制备非晶NiFe纳米片,作为OER的高效电催化剂。该方法制备a-NiFe NS/IF仅需200 s,电催化剂具有优异的催化活性,在1.0 M KOH条件下,只需要211和240 mV左右的过电位就能达到10和100 mA cm(-2)电流密度。(C) 2019科学出版社,中国科学院大连化学物理研究所。由Elsevier B.V.和科学出版社出版。版权所有。
The earth-abundant transition metal based nanomaterials are regarded as state-of-the-art oxygen evolution reaction (OER) electrocatalyst. Recent studies have shown that amorphous materials are more active than their crystalline forms. Herein, we demonstrate a facile and rapid substrate participation method to fabricate amorphous NiFe nanosheets on iron foam (a-NiFe NS/IF) at ambient temperature as a highly efficient electrocatalyst for OER. This method only takes 200 s to fabricate the a-NiFe NS/IF and the electrocatalyst possesses excellent catalytic activities which only needs overpotentials of about 211 and 240 mV to reach 10 and 100 mA cm(-2) current densities in 1.0 M KOH. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.