Activation of an Aryl C−H Bond Converts Chelating Diphenolate Ligands Bound to Zirconium into Trianionic Pincer Ligands: σ-Donor Ligand Effects versus Thermolysis
Activation of an Aryl C−H Bond Converts Chelating Diphenolate Ligands Bound to Zirconium into Trianionic Pincer Ligands: σ-Donor Ligand Effects versus Thermolysis
复制标题
芳基 C−H 键的激活将与锆结合的螯合二酚配体转化为三阴离子钳配体：σ-供体配体效应与热解作用
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发表时间：
2010
期刊：
影响因子：
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通讯作者：
A. Veige
中科院分区：
文献类型：
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作者：
S. Kuppuswamy;I. Ghiviriga;K. Abboud;A. Veige
本文报道了一种三阴离子钳形配体负载的新型锆苄基配合物的合成和表征。...='class10'>三联苯二醇[tBuOCO]H3（1）在苯甲酸中处理Zr（CH_2Ph）_4，得到了较好的结果.
This report describes the synthesis and characterization of new zirconium benzyl complexes supported by a trianionic pincer ligand. Treating Zr(CH2Ph)4 with the terphenyldiol [tBuOCO]H3 (1) in benz...