Influence of dehydration on the electron spin resonance in the Cu3[W(CN)8]2(Pyrimidine)2 · 8H2O molecular magnet

Influence of dehydration on the electron spin resonance in the Cu3[W(CN)8]2(Pyrimidine)2 · 8H2O molecular magnet
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脱水对Cu3[W(CN)8]2(嘧啶)2·8H2O分子磁体电子自旋共振的影响

DOI:
10.1134/s1063783413050168
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发表时间:
2013
影响因子:
0.6
通讯作者:
R. Morgunov
R. Morgunov
中科院分区:
物理与天体物理4区
文献类型:
--
作者:
O. Koplak;M. Kirman;A. Dmitriev;H. Tokoro;S. Ohkoshi;R. Morgunov

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发现了脱水对Cu3[W(CN)8]2(嘧啶)2·8H2O分子磁体电子自旋共振谱的影响。已经确定,晶体中存在两个居里温度分别为~12-17 和~50 K 的铁磁相,对应于两条不同的铁磁共振谱线。脱水导致低温相的居里温度从 12 K 增加到 17 K,并改变高温相的光谱参数(共振场和宽度线)的温度依赖性。
The influence of dehydration on the electron spin resonance spectra in the Cu3[W(CN)8]2(pyrimidine)2· 8H2O molecular magnet has been found. It has been established that two ferromagnetic phases with the Curie temperatures of ∼12–17 and ∼50 K, which correspond to two different lines of the ferromagnetic resonance, are present in crystals. Dehydration leads to increasing the Curie temperature of the low-temperature phase from 12 to 17 K and to varying the temperature dependences of the spectrum parameters of the high-temperature phase (the resonant field and the width line).
[{Cr(CN)6}{Mn(S)-pnH-(H2O)}]·H2O单晶分子亚铁磁体中的磁共振
DOI: --
发表时间: 2005
期刊: Physics Of The Solid State 47
影响因子: --
作者:
Blokhin IV;Markosyan AS;Morgunov RB;Inoue K;Tanimoto Y;Yoshida Y
通讯作者: Yoshida Y