SPORIDESMINS .16. STRUCTURE OF CHETOMIN, A TOXIC METABOLITE OF CHAETOMIUM-COCHLIODES, BY N-15 AND C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY

SPORIDESMINS .16. STRUCTURE OF CHETOMIN, A TOXIC METABOLITE OF CHAETOMIUM-COCHLIODES, BY N-15 AND C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY
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DOI：
10.1039/p19780001248
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发表时间：
1978-01-01
期刊：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
影响因子：
--
通讯作者：
KIS, ZL
KIS, ZL
中科院分区：
其他
文献类型：
--
作者：
BREWER, D;MCINNES, AG;KIS, ZL

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Chetomin, atoxic metabolite, may be associated with poor growth in ruminants. Analysis of the 13C and 15N NMR spectra of [15N6]chetomin biosynthesized by C. cochliodes establishes that the sporidesmin-like and 3-(.omega.-skatyl)-3,6-epidithiopiperazine-2,5-dione fragments are linked by a bond between the indole N and the quaternary .beta.-indoline C.