Fe-catalysed oxidative C-H functionalization/C-S bond formation.
Fe-catalysed oxidative C-H functionalization/C-S bond formation.
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DOI：
10.1039/c1cc16184a
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发表时间：
2012-01
影响因子：
4.9
通讯作者：
Haibo Wang;Lu Wang;J. Shang;Xingqi Li;Haoyuan Wang;J. Gui;A. Lei
中科院分区：
文献类型：
--
作者：
Haibo Wang;Lu Wang;J. Shang;Xingqi Li;Haoyuan Wang;J. Gui;A. Lei
使用铁作为催化剂，在温和条件下直接进行 C-H 官能化/C-S 键形成。各种底物都可以以中等至优异的产率提供苯并噻唑。初步的机理研究表明，吡啶对于高产率和选择性起着至关重要的作用。
Iron was used as the catalyst for the direct C-H functionalization/C-S bond formation under mild conditions. Various substrates could afford benzothiazoles in moderate to excellent yields. Preliminary mechanistic studies revealed that pyridine played a crucial role for the high yields and selectivities.