A Copper(I)-Catalyzed Three-Component Domino Process: Assembly of Complex 1,2,3-Triazolyl-5-Phosphonates from Azides, Alkynes, and H-Phosphates
A Copper(I)-Catalyzed Three-Component Domino Process: Assembly of Complex 1,2,3-Triazolyl-5-Phosphonates from Azides, Alkynes, and H-Phosphates
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铜 (I) 催化的三组分多米诺过程：从叠氮化物、炔烃和 H-磷酸酯组装复杂的 1,2,3-三唑基-5-磷酸酯
DOI：
10.1002/chem.201303324
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发表时间：
2013-10-18
影响因子：
4.3
通讯作者：
Zhang, Lihe
中科院分区：
文献类型：
--
作者：
Li, Lingjun;Hao, Guoliang;Zhang, Lihe
Three is better than one! A new copper-catalyzed tricomponent reaction of a terminal alkyne, organic azide, and H-phosphate (CuAA[P]C) leads to a structurally diverse polysubstituted 1,2,3-triazolyl-5-phosphonate, which provides an efficient tool for the direct introduction of phosphonic acid groups by a "click reaction" (see scheme).
