Self-organization C60 nanoparticles in toluene solution
Self-organization C60 nanoparticles in toluene solution
复制标题
甲苯溶液中的自组织 C60 纳米颗粒
DOI：
10.1016/s0167-7322(01)00228-8
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发表时间：
2001
影响因子：
6
通讯作者：
P. Scharff
中科院分区：
文献类型：
--
作者：
L. Bulavin;I. Adamenko;V. Yashchuk;T. Y. Ogul'chansky;Y. Prylutskyy;S. Durov;P. Scharff
对富勒烯C60在甲苯溶液中的结构进行了详细的实验和理论研究。发现C60在室温下即使在浓度为0.18~0.78g/L的相当稀的溶液中也能缓慢聚集。得到的电子吸收光谱证实了吸收的主要分子特征。聚集动力学结果表明，C60聚集体的结构可描述为一个分形系统。数值计算预测了在甲苯溶液中形成稳定的富勒烯(C60)N团簇，其尺寸为>；1.2 nm，聚集数N≥为3。
The structure of fullerene C60in toluene solution was investigated both experimentally and theoretically in detail. C60was found to aggregate slowly even in fairly dilute solution concentrations ranging from 0.18 to 0.78 g/l at room temperature. The electronic absorption spectra obtained testify to the mainly molecular character of absorption. The aggregation kinetics results indicated that the structure of C60aggregates could be described as a fractal system. The numerical calculations predicted the formation of stable fullerene (C60)Nclusters in toluene solution with sizes >1.2 nm and aggregation number N≥3.
DOI：
10.1016/b978-0-12-221820-0.x5000-x
发表时间：
1996
期刊：
--
影响因子：
--
作者：
L. B. Ebert
通讯作者：
L. B. Ebert