Preparations and Reactions with Amines of Some 1,2-Dibenzoylalkenes
Preparations and Reactions with Amines of Some 1,2-Dibenzoylalkenes
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DOI：
10.1021/jo01109a011
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发表时间：
1956-03
影响因子：
3.6
通讯作者：
P. Bailey;S. S. Bath-S.;William F. Thomsen;H. Nelson;Elias E. Kawas
中科院分区：
文献类型：
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作者：
P. Bailey;S. S. Bath-S.;William F. Thomsen;H. Nelson;Elias E. Kawas
比较了几种二苯甲酰基烯烃与胺的反应和1，2-二苯甲酰基丙烯与胺的反应，得到1-氨基-2，3-二苯甲酰基丙烷。3-苯甲酰基-2，5-二苯基呋喃经Wolff-Kishner还原得到3，5-二苯基-4-（4-甲氧基苯基）-3，5-二苯基呋喃。在较早的文献中，1，2-二苯甲酰基-丙烯、2，1，2-二苯甲酰基-1-丁烯、3和2，3-二苯甲酰基-1-丁烯的反应被描述，将1，2-二苯甲酰基-3-（4-吗啉基）-2-丁烯4与吗啉反应，得到1，2-二苯甲酰基-3-（4-吗啉基）-2-丁烯4。（4-吗啉基）丙烷和丁烷以及2，3-二苯甲酰基-1，4-二将1，2-二苯甲酰基丙烯与卤化氢反应，得到1，2-二苯甲酰基-3-（4-吗啉基）-丁烷，
The reactions of several dibenzoylalkenes with amines are compared with the reaction of 1, 2-dibenzoylpropene with amines to give l-amino-2, 3-dibenzoylpropanes. The Wolff-Kishner reduction of 3-benzoyl-2, 5-diphenylfuran gave 3, 5-diphenyl-4-(ß-phenylethyl) pyrazóle as a by-product.In earlier papers the reactions of 1, 2-dibenzoyl-propene, 2 1, 2-dibenzoyl-l-butene, 3 and 2, 3-diben-zoyl-l-(4-morpholinyl)-2-butene4 with morpholine to give l, 2-dibenzoyl-3-(4-morpholinyl) propane and butane and 2, 3-dibenzoyl-l, 4-di (4-morpholinyl)-butane, respectively, and of 1, 2-dibenzoylpropene with hydrogen halides to give l, 2-dibenzoyl-3-