Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture
Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture
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DOI：
10.1021/ic8007798
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发表时间：
2008-07-07
影响因子：
4.6
通讯作者：
Bu, Xianhui
中科院分区：
文献类型：
--
作者：
Chen, Shumei;Zhang, Jian;Bu, Xianhui
用离子热法合成了一种新型的有机模板纯手性材料（EMIm）[Co2-（D-cam）（2）（ac）]（1; D-H（2）cam = D-辛酸; ac =乙酸; EMIm = 1-乙基-3-甲基咪唑），它具有独特的乙酸根-柱撑钴-辛酸根结构，将离子液体的阳离子组分包裹起来。
A new organically templated homochiral material (EMIm)[Co2-(D-cam)(2)(ac)] (1; D-H(2)cam = D-camphoric acid; ac = acetate; EMIm = 1-ethyl-3-methylimidazolium) has been ionothermally synthesized, and it features an unusual acetate-pillared cobalt-camphorate architecture encapsulating the cationic component of the ionic liquid.