Eight-membered ring formation via olefin insertion into a carbon-carbon single bond
Eight-membered ring formation via olefin insertion into a carbon-carbon single bond
复制标题
DOI：
10.1246/cl.2004.876
复制
发表时间：
2004-07-05
影响因子：
1.6
通讯作者：
Murakami, M
中科院分区：
文献类型：
--
作者：
Matsuda, T;Fujimoto, A;Murakami, M
用催化量的铑-膦配合物处理2位有邻苯乙烯基的环丁酮，通过在环丁酮的C-C单键中插入C=C键，得到八元环酮。
Treatment of cyclobutanone having an o-styryl group at the 2-position with a catalytic amount of rhodium-phosphine complex afforded eight-membered ring ketones via intramolecular insertion of the C=C bond into the C-C single bond of the cyclobutanone.