Visible-Light-Driven Dehydrogenative Coupling of Primary Alcohols with Phenols Forming Aryl Carboxylates
Visible-Light-Driven Dehydrogenative Coupling of Primary Alcohols with Phenols Forming Aryl Carboxylates
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可见光驱动伯醇与酚的脱氢偶联形成芳基羧酸酯
DOI：
10.1021/acs.orglett.1c03017
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发表时间：
2021
期刊：
影响因子：
5.2
通讯作者：
Murakami Masahiro
中科院分区：
文献类型：
--
作者：
Kawasaki Tairin;Tosaki Tomohiro;Ishida Naoki;Murakami Masahiro
开发了一种从脂肪族伯醇和酚获得芳基酯的制备方法。该反应在可见光照射下在环境温度下进行，无需任何氧化剂或氢受体。具有多种官能团的伯醇与苯酚成功酯化。所产生的酯可用作各种羰基化合物的前体。
A preparative method for obtaining aryl esters from aliphatic primary alcohols and phenols was developed. The reaction proceeds under the irradiation of visible light at ambient temperature, dispensing with any oxidant or hydrogen acceptor. Primary alcohols having a variety of functional groups are successfully esterified with phenols. The produced esters can be utilized as the precursor of various carbonyl compounds.