Isolation of a MnIV acylperoxo complex and its monooxidation ability
Isolation of a MnIV acylperoxo complex and its monooxidation ability
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DOI：
10.1039/c3cc43447h
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Ogo, Seiji
中科院分区：
文献类型：
--
作者：
Kikunaga, Takahiro;Matsumoto, Takahiro;Ogo, Seiji
本文描述了高价Mn-IV配合物与过氧化物单氧作用的第一个例子。采用电喷雾质谱和共振拉曼光谱直接观察了以间氯过氧苯甲酸为氧给体的Mn-IV酰基过氧中间体。
The first example of monooxygenation by a high-valent Mn-IV complex with a peroxide is described. A key Mn-IV acylperoxo intermediate, which uses m-chloroperoxybenzoic acid as the oxygen donor, is directly observed by electro-spray ionization mass spectrometry and resonance Raman spectroscopy.