Recent Developments in the Application of Organocatalysis to Glycosylations

Recent Developments in the Application of Organocatalysis to Glycosylations
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DOI:
10.1055/s-0033-1338970
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发表时间:
2013-11-12
期刊:
影响因子:
2
通讯作者:
McGarrigle, Eoghan M.
McGarrigle, Eoghan M.
中科院分区:
化学4区
文献类型:
--
作者:
Balmond, Edward I.;Galan, M. Carmen;McGarrigle, Eoghan M.

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糖苷键的区域选择性和立体选择性合成仍然是有机合成中最具挑战性的领域之一。尽管有机催化在不对称合成中得到了广泛的应用,但它在低聚糖合成中的应用仍处于起步阶段。这篇文章强调了最近一些用于区域和立体选择性糖基化的有机催化剂的例子,并展望了该领域的未来。
The regioselective and stereoselective synthesis of glycosidic bonds still remains one of the most challenging areas within organic synthesis. Despite the broad use of organocatalysis within asymmetric synthesis, its application towards oligosaccharide synthesis is still in its infancy. This article highlights some recent examples of organocatalysts being used for regio- and stereoselective glycosylations and looks towards the future of the area.