Self-electrochemiluminescence of CdTe nanocrystals capped with 2-diethylaminoethanethiol

Self-electrochemiluminescence of CdTe nanocrystals capped with 2-diethylaminoethanethiol
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2-二乙氨基乙硫醇封端的 CdTe 纳米晶的自电化学发光

DOI:
10.1039/c7cc01955f
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发表时间:
2017
影响因子:
4.9
通讯作者:
Ding S.-N.
Ding S.-N.
中科院分区:
化学2区
文献类型:
--
作者:
Han T.-T.;Dong H.;Ren L.-L.;Bao N.;Wu W.;Ding S.-N.

文献摘要

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首次将二乙基氨基乙烷(DEAET)与3-巯基丙酸(MPA)封端的CdTe纳米晶(CdTe-MPA NCs)进行交换,成功合成了DEAET保护的CdTe纳米晶(CdTe-DEAET NCs)。结果表明,CdTe-DEAET纳米粒子的紫外-可见吸收光谱和光致发光光谱均发生明显蓝移,纳米粒子的粒径减小,并具有较强的阳极电致发光。
We successfully synthesized 2-diethylaminoethanethiol (DEAET)-protected CdTe nanocrystals (CdTe-DEAET NCs) by exchanging DEAET onto 3-mercaptopropionic acid (MPA)-capped CdTe NCs (CdTe-MPA NCs) for the first time. Noticeable blue-shifts on the UV-vis absorption and photoluminescence spectra, the decrease of particle sizes and strong anodic ECL emission from CdTe-DEAET NCs were observed.