Characterization of Ultrathin Films of Chloroaluminum Phthalocyanine during Layer-by-Layer Preparation on Graphite: PIES and UPS Study
Characterization of Ultrathin Films of Chloroaluminum Phthalocyanine during Layer-by-Layer Preparation on Graphite: PIES and UPS Study
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石墨上逐层制备过程中氯铝酞菁超薄膜的表征：PIES 和 UPS 研究
DOI：
10.1021/j100034a026
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发表时间：
1995
期刊：
影响因子：
--
通讯作者：
Y. Maruyama
中科院分区：
文献类型：
--
作者：
T. Pasinszki;M. Aoki;S. Masuda;Y. Harada;N. Ueno;H. Hoshi;Y. Maruyama
利用Penning电离电子能谱和紫外光电子能谱对石墨衬底上逐层真空沉积酞菁氯铝的超薄膜（一至多层）进行了表征。在一个单层中，在室温下沉积在衬底上的分子与衬底平取向，氯原子突出在薄膜表面外。随着膜厚的增加，分子在后续层中逐渐倾斜。在-170℃下沉积在衬底上的单层薄膜显示出无序的分子排列（倾斜分子），但在将薄膜加热到100℃时，可以观察到排列从无序（倾斜）到有序（平坦）的变化。
Penning ionization electron spectroscopy and ultraviolet photoelectron spectroscopy were used to characterize ultrathin films (one to several monolayers) of chloroaluminum phthalocyanine during layer-by-layer vacuum deposition onto a graphite substrate. At one monolayer, molecules deposited on the substrate held at room temperature are oriented flat to the substrate with the chlorine atom protruding outside the film surface. With increasing film thickness, molecules are gradually tilted in subsequent layers. The monolayer film deposited on the substrate at -170 "C shows a disordered molecular arrangement (tilted molecules), but the change in the arrangement, disordered (tilted) to ordered (flat), is observed upon heating the film up to 100 "C.