Electrolyte Interphases in Aqueous Batteries
Electrolyte Interphases in Aqueous Batteries
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水系电池中的电解质界面
DOI：
10.1002/anie.202312585
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发表时间：
2023
期刊：
影响因子：
--
通讯作者：
Ji, Xiulei
中科院分区：
文献类型：
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作者：
Sui, Yiming;Ji, Xiulei
水的窄电化学稳定窗口对水性电解质的发展提出了挑战。与非水电解质相反，水电解的产物不会在电极上形成钝化层。因此，水性电解质需要另外的组分（例如添加剂和共溶剂）的反应，以促进在阳极上形成所需的固体电解质界面（SEI）和在阴极上形成阴极电解质界面（CEI）。本文综述了水溶液电池中电解质界面相生成的基本原理和最新进展。
The narrow electrochemical stability window of water poses a challenge to the development of aqueous electrolytes. In contrast to non‐aqueous electrolytes, the products of water electrolysis do not contribute to the formation of a passivation layer on electrodes. As a result, aqueous electrolytes require the reactions of additional components, such as additives and co‐solvents, to facilitate the formation of the desired solid electrolyte interphase (SEI) on the anode and cathode electrolyte interphase (CEI) on the cathode. This review highlights the fundamental principles and recent advancements in generating electrolyte interphases in aqueous batteries.