The enhanced catalytic activity and stability of oxodiperoxomolybdenum-modified mesoporous organosilicas in selective epoxidation reactions
The enhanced catalytic activity and stability of oxodiperoxomolybdenum-modified mesoporous organosilicas in selective epoxidation reactions
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氧化二过氧钼改性介孔有机硅在选择性环氧化反应中增强的催化活性和稳定性
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发表时间：
2009
期刊：
影响因子：
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通讯作者：
W. Thiel
中科院分区：
文献类型：
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作者：
S. Shylesh;Mingjun Jia;Andreas Seifert;Sridhar Adappa;Stefan Ernst;W. Thiel
与MCM-41衍生的体系相比，（L-L）MoO（O2）2型配合物在以H2 O2为氧化剂的液相环氧化反应中表现出10倍的催化活性和高稳定性。
Complexes of the type (L–L)MoO(O2)2 heterogenized on phenylene-bridged mesoporous organosilicas show a 10-fold increase in catalytic activity and a high stability in liquid phase epoxidation reactions, with H2O2 as the oxidant, compared to the corresponding MCM-41-derived systems.