Self-assembled 3D flowerlike iron oxide nanostructures and their application in water treatment

Self-assembled 3D flowerlike iron oxide nanostructures and their application in water treatment
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DOI:
10.1002/adma.200600504
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发表时间:
2006-09-18
期刊:
影响因子:
29.4
通讯作者:
Wan, Li-Jun
Wan, Li-Jun
中科院分区:
材料科学1区
文献类型:
--
作者:
Zhong, Liang-Shu;Hu, Jin-Song;Wan, Li-Jun

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采用乙二醇法自组装工艺,用廉价无毒的三氯化铁合成了3D花状氧化铁纳米结构(见图)。在氧化铁前驱体的形态演变过程中,确定了一个两阶段的生长过程。具有相同花状结构的α-Fe_2O_3、γ-Fe_2O_3和Fe_3O_4很容易从相同的前驱体中获得,但经过不同的焙烧程序。所得到的氧化铁对水中各种污染物具有很好的去除能力。
An ethylene-glycol-mediated self-assembly process is adopted to synthesize 3D flowerlike nanostructures of iron oxide (see figure) using inexpensive and nontoxic ferric chloride. A two-stage growth process is identified during the morphological evolution of the iron oxide precursor. alpha-Fe2O3, gamma-Fe2O3, and Fe3O4 with the same flowerlike structure are readily obtained from the same precursor but by different calcination procedures. The as-obtained iron oxides show excellent ability to remove various pollutants from water.