Anodic methoxylation and acetoxylation of imines and imidates
Anodic methoxylation and acetoxylation of imines and imidates
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DOI：
10.1016/s0040-4039(03)00548-3
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发表时间：
2003-04-07
影响因子：
1.8
通讯作者：
Fuchigami, T
中科院分区：
文献类型：
--
作者：
Baba, D;Fuchigami, T
环亚胺酯，2-芳基-2-恶唑啉，在甲醇中的阳极氧化提供相应的4-甲氧基化产物。还使用溴离子介体实现了来自甘氨酸酯和二苯甲酮的开链亚胺的阳极α-甲氧基化和α-乙酰氧基化。另一方面，不使用溴介体，含CF 3的亚胺和亚氨酸盐的阳极α-乙酰氧基化是成功的。这是第一个成功的亚胺和亚胺酯的阳极α-取代的例子。(C)2003爱思唯尔科技有限公司版权所有。
Anodic oxidation of cyclic imidates, 2-aryl-2-oxazolines, in methanol provided the corresponding 4-methoxylated products. Anodic alpha-methoxylation and alpha-acetoxylation of open-chain imines derived from glycine esters and benzophenone were also achieved using a bromide ion mediator. On the other hand, anodic a-acetoxylation of CF3-containing imine and imidate was successful without use of the bromine mediator. This is the first example of successful anodic a-substitution of imines and imidates. (C) 2003 Elsevier Science Ltd. All rights reserved.