Formation of Metallophosphenium Cluster Complexes: Synthesis and Structure of Cp(Ph)[N(SiMe3)2]†
Formation of Metallophosphenium Cluster Complexes: Synthesis and Structure of Cp(Ph)[N(SiMe3)2]†
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金属磷鎓簇配合物的形成：Cp(Ph)[N(SiMe3)2]†的合成和结构
DOI：
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发表时间：
1996
期刊：
影响因子：
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通讯作者：
R. Paine
中科院分区：
文献类型：
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作者：
Hansulrich Reisacher;E. Duesler;R. Paine
[(Me3Si)2N](Ph)PW(CO)2Cp与Fe2(CO)9反应生成双金属化合物Cp(Ph)[N(SiMe3)2]，产率较高，通过质谱、IR、1H-、31P-NMR和单晶x射线衍射分析对其进行了表征。分子结构由Fe(CO)3和CpW(CO)2片段组成，由一个桥接的CO配体和一个组成四元双环结构的磷离子片段连接。
The reaction of [(Me3Si)2N](Ph)PW(CO)2Cp with Fe2(CO)9 produces in good yield the bimetallic compound Cp(Ph)[N(SiMe3)2] that was characterized by mass spectrometry, IR, 1H-, and 31P-NMR spectroscopy, and single crystal X-ray diffraction analysis. The molecular structure consists of Fe(CO)3 and CpW(CO)2 fragments joined by a bridging CO ligand and a phosphenium ion fragment which comprise a four-membered bicyclic structure.