Sequential bond energies of chromium carbonyls (Cr(CO)x+, x = 1-6)
Sequential bond energies of chromium carbonyls (Cr(CO)x+, x = 1-6)
复制标题
羰基铬的连续键能 (Cr(CO)x , x = 1-6)
DOI:
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发表时间:
1993
期刊:
影响因子:
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通讯作者:
P. Armentrout
中科院分区:
文献类型:
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作者:
Farooq A. Khan;D. Clemmer;R. Schultz;P. Armentrout
The sequential bond energies of Cr(CO) x + , x=1-6, are determined by collision-induced dissociation in a guided ion beam tandem mass spectrometer. Values for the 0 K bond energies (in eV) are determined to be D(Cr + -CO)=0.93±0.04, D[(CO)Cr + -CO]=0.98±0.03, D[(CO) 2 Cr + -CO]=0.56±0.06, D[(CO) 3 Cr + -CO]=0.53±0.08, D[(CO) 4 Cr + -CO]=0.64±0.03, and D[(CO) 5 Cr + -CO]=1.35±0.08