Crystal structures of (R,R)-{[Ph(Me)CH]2NLi•pmdeta} and {[PhC(=CH2)NH]Na•pmdeta}2:: alkali metal amides derived from (R,R)-bis(α-methylbenzyl)amine
Crystal structures of (R,R)-{[Ph(Me)CH]2NLi•pmdeta} and {[PhC(=CH2)NH]Na•pmdeta}2:: alkali metal amides derived from (R,R)-bis(α-methylbenzyl)amine
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DOI：
10.1039/b007482i
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发表时间：
2001-01-01
影响因子：
4.9
通讯作者：
Nichols, PJ
中科院分区：
文献类型：
--
作者：
Andrews, PC;Duggan, PJ;Nichols, PJ
（BuM）-M-n （M = Li, Na）与[(R，R)]-双（α -甲基苄基）胺在pmdeta存在下反应生成手性锂酰胺配合物（R，R）-{[Ph(Me)CH](2)NLi。而更值得注意的是，胺酸钠{[PhC(=CH2)NH]Na。pmdeta} (2);两种化合物均经单晶x射线衍射证实。
The reaction of (BuM)-M-n (M = Li, Na) with [(R,R)]-bis(alpha -methylbenzyl)amine in the presence of pmdeta results in the formation of the chiral lithium amide complex (R,R)-{[Ph(Me)CH](2)NLi . pmdeta} and, remarkably, the sodium enamide, {[PhC(=CH2)NH]Na . pmdeta}(2); both compounds have been authenticated by single crystal X-ray diffraction.