Four coordination polymers constructed from a multicarboxylate ligand and metal centers various from Ba2+, Cu2+, Zn2+ to Gd3+: Syntheses, crystal structures and properties
Four coordination polymers constructed from a multicarboxylate ligand and metal centers various from Ba2+, Cu2+, Zn2+ to Gd3+: Syntheses, crystal structures and properties
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由多羧酸盐配体和 Ba2 、 Cu2 、 Zn2 到 Gd3 等金属中心构成的四种配位聚合物：合成、晶体结构和性能
DOI：
10.1016/j.ica.2008.11.012
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发表时间：
2009-05
影响因子：
2.8
通讯作者：
Li, Yi-zhi
中科院分区：
文献类型：
--
作者：
Zang, Shuang-quan;Lin, Jian-guo;Gao, Song;Meng, Qing-jin;Su, Yang;Li, Yi-zhi
Hydrothermal reactions between H4ODPA (2,2′,3,3′-oxydiphthalic acid) and metal ion salts of Ba2+, Cu2+, Zn2+and Gd3+afford four novel coordination polymers [Ba(H2ODPA)(H2O)4]·H2O (1), [Cu2(ODPA)(H2O)3]·H2O (2), Zn2(ODPA)(H2O)2(3) and [Gd(HODPA)(H2O)3.5]·H2O (4), accordingly. These polymers show great differences in regard to their structures and properties originated from the variation of size and coordination geometry of the metal ions. Compound 1 presents puckered achiral layer structure with (4.82) topology with helices, 2 has a 63topology with copper tetramer as SBUs, 3 has chiral layer with two kinds of helices built up from Zn-binuclear “paddle-wheel” like SBUs, and 4 features a simple 1D helix with opposite chirality. Compound 3 shows obvious fluorescent emissions upon excitation. Compound 2 shows ferromagnetic interactions between CuIIcenters bridged by carboxylate groups, whereas compound 4 presents weak ferromagnetic interaction between GdIIIions.
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影响因子：
3.8
作者：
Shuangquan Zang;Yang Su;You Song;Yi-zhi Li;Z. Ni;and Huizhen Zhu;Q. Meng
通讯作者：
Shuangquan Zang;Yang Su;You Song;Yi-zhi Li;Z. Ni;and Huizhen Zhu;Q. Meng
影响因子：
64.8
作者：
Li, H;Eddaoudi, M;Yaghi, OM
通讯作者：
Yaghi, OM
影响因子：
4.6
作者：
J. Pasán;J. Sanchiz;C. Ruiz-Pérez;F. Lloret;M. Julve
通讯作者：
J. Pasán;J. Sanchiz;C. Ruiz-Pérez;F. Lloret;M. Julve
影响因子：
--
作者：
Yan‐Zhen Zheng;M. Tong;Wei-Xiong Zhang;Xiao‐Ming Chen
通讯作者：
Yan‐Zhen Zheng;M. Tong;Wei-Xiong Zhang;Xiao‐Ming Chen
影响因子：
4.6
作者：
Shuangquan Zang;Yang Su;Yi-zhi Li;Z. Ni;Q. Meng
通讯作者：
Shuangquan Zang;Yang Su;Yi-zhi Li;Z. Ni;Q. Meng