Phosphonium-Based Ionic Liquids: An Overview
Phosphonium-Based Ionic Liquids: An Overview
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DOI：
10.1071/ch08558
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发表时间：
2009-01-01
影响因子：
1.1
通讯作者：
MacFarlane, Douglas R.
中科院分区：
文献类型：
--
作者：
Fraser, Kevin J.;MacFarlane, Douglas R.
基于鏻阳离子的离子液体（IL）是容易获得的IL家族，其在某些应用中提供与基于氮阳离子的IL相比上级的性质。最近研究的应用包括它们作为萃取溶剂、化学合成溶剂、电池和超级电容器中的电解质以及腐蚀保护的用途。与此同时，近年来商业上可获得的阳离子-阴离子组合的范围也在增加。在这里，我们提供了这些有趣的材料的特性和它们出现的应用的概述。
Phosphonium cation-based ionic liquids (ILs) are a readily available family of ILs that in some applications offer superior properties as compared to nitrogen cation-based ILs. Applications recently investigated include their use as extraction solvents, chemical synthesis solvents, electrolytes in batteries and super-capacitors, and in corrosion protection. At the same time the range of cation-anion combinations available commercially has also been increasing in recent years. Here, we provide an overview of the properties of these interesting materials and the applications in which they are appearing.