Copper-catalyzed stereospecific N-allenylations of amides. Syntheses of optically enriched chiral allenamides.
Copper-catalyzed stereospecific N-allenylations of amides. Syntheses of optically enriched chiral allenamides.
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DOI：
10.1021/ol051094q
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发表时间：
2005-06
期刊：
影响因子：
5.2
通讯作者：
Lichun Shen;R. Hsung;Yanshi Zhang;J. Antoline;Xuejun Zhang
中科院分区：
文献类型：
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作者：
Lichun Shen;R. Hsung;Yanshi Zhang;J. Antoline;Xuejun Zhang
本文描述了用催化铜(I)盐和N，N'-二甲基亚甲二胺对光学富集的碘化烯丙烯进行立体特异性酰胺化合成手性烯丙烯酰胺。
[reaction: see text] Syntheses of chiral allenamides via a stereospecific amidation of optically enriched allenyl iodides using catalytic copper(I) salt and N,N'-dimethylethylene-diamine are described here.