Determination of Abraham model solute descriptors for benzoin based on measured solubility ratios
Determination of Abraham model solute descriptors for benzoin based on measured solubility ratios
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根据测量的溶解度比确定安息香的亚伯拉罕模型溶质描述符
DOI：
10.1080/00319104.2011.637628
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发表时间：
2012
影响因子：
1.2
通讯作者：
M. Abraham
中科院分区：
文献类型：
--
作者：
Timothy W. Stephens;M. Loera;Monica Calderas;Ricardo Diaz;Nicholas Montney;W. Acree;M. Abraham
本文报道了298.15 K下安息香在1个氯代烷、15个醇、5个芳香烃、5个烷基乙酸酯、5个烷氧醇和3个醚中的溶解度，并与亚伯拉罕溶剂化参数模型进行了数学关联。为安息香计算的溶质描述符描述了实验摩尔溶解度数据，总体平均标准偏差为0.097 单位。
Experimental solubilities are reported for benzoin dissolved in 1 chloroalkane, 15 alcohols, 5 aromatic hydrocarbons, 5 alkyl acetates, 5 alkoxyalcohols and 3 ethers at 298.15 K. The measured solubility data were mathematically correlated with the Abraham solvation parameter model. The solute descriptors that were calculated for benzoin describe the experimental molar solubility data to within an overall average standard deviation of 0.097 log units.