Conjugated Polymer Synthesis via Catalyst-Transfer Polycondensation (CTP): Mechanism, Scope, and Applications
Conjugated Polymer Synthesis via Catalyst-Transfer Polycondensation (CTP): Mechanism, Scope, and Applications
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DOI：
10.1021/ma401314x
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发表时间：
2013-11-12
期刊：
影响因子：
5.5
通讯作者：
McNeil, Anne J.
中科院分区：
文献类型：
--
作者：
Bryan, Zachary J.;McNeil, Anne J.
最近发现了一种合成π共轭聚合物的活性、可控链生长方法，点燃了这一领域，并导致了许多新材料的开发。这一观点侧重于综合转化的机制基础，突出了有争议的假设和支持数据。对文献的批判性分析表明，单体范围在很大程度上仍然局限于富电子单体。最后，简要概述了一些令人兴奋的新材料，通过这种方法获得。
The recent discovery of a living, controlled chain-growth method for synthesizing pi-conjugated polymers has ignited the field and led to the development of many new materials. This Perspective focuses on the mechanistic underpinnings of the synthetic transformation, highlighting the controversial hypotheses and supporting data. A critical analysis of the literature revealed that the monomer scope remains largely limited to electron-rich monomers at this time. Last, a brief overview of some exciting new materials accessed via this method is provided.