Tuning photochemical properties of phosphorus(V) porphyrin photosensitizers
Tuning photochemical properties of phosphorus(V) porphyrin photosensitizers
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DOI：
10.1039/c7cc06052a
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发表时间：
2017-09-14
影响因子：
4.9
通讯作者：
Hosseini, Mir Wais
中科院分区：
文献类型：
--
作者：
Meshkov, Ivan N.;Bulach, Veronique;Hosseini, Mir Wais
研究了P(V)卟啉的光敏和发射特性。轴向配体的性质，占据P中心的顶端位置，采用八面体配位几何形状，强烈影响单线态氧的生成和电荷转移，并允许在两个过程之间切换。
Photosensitizing and emission properties of P(V) porphyrins were studied. The nature of the axial ligands, occupying the apical position on the P centre adopting an octahedral coordination geometry, strongly influences singlet oxygen generation and charge transfer and allows switching between the two processes.