Palladium Catalyzed Insertion Reaction of Isocyanides with 3-Arylisoxazol-5(4H)-ones: Synthesis of 4-Aminomethylidene Isoxazolone Derivates
Palladium Catalyzed Insertion Reaction of Isocyanides with 3-Arylisoxazol-5(4H)-ones: Synthesis of 4-Aminomethylidene Isoxazolone Derivates
复制标题
钯催化异氰化物与 3-芳基异恶唑-5(4H)-酮的插入反应：4-氨基亚甲基异恶唑酮衍生物的合成
DOI：
10.1021/acs.joc.9b01585
复制
发表时间：
2019
影响因子：
3.6
通讯作者：
Ji Shun Jun
中科院分区：
文献类型：
--
作者：
Zhu Yi Ming;Xu Pei;Wang Shun Yi;Ji Shun Jun
A palladium catalyzed insert reaction of isocyanides to 3-arylisoxazol-5(4H)-ones for the construction of 4-aminomethylidene isoxazolone derivates is reported. In this transformation, only the C–H bond of the methylene group was involved while the remaining ring structure was retained. In general, this work provided a new protocol for the synthesis of 4-aminomethylidene isoxazolones.
