Comparative Investigation of Electrocatalytic Oxidation of Cyclohexene by Proton-Exchange Membrane and Anion-Exchange Membrane Electrolyzers
Comparative Investigation of Electrocatalytic Oxidation of Cyclohexene by Proton-Exchange Membrane and Anion-Exchange Membrane Electrolyzers
复制标题
质子交换膜和阴离子交换膜电解槽电催化氧化环己烯的对比研究
DOI：
10.1055/a-2000-8231
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发表时间：
2022
期刊：
影响因子：
--
通讯作者：
Shimizu Yugo
中科院分区：
文献类型：
--
作者：
Shida Naoki;Atobe Mahito;Ido Yuto;Shimizu Yugo
环己烯的电催化氧化在质子交换膜（PEM）和阴离子交换膜（AEM）电解槽中进行。为了实现高效的电催化氧化，对阳极催化剂材料、施加的电势和所用的溶剂进行了优化。此外，澄清了 PEM 和 AEM 电解槽之间反应性的差异，并提出了每种电解槽中环己烯氧化的机理。
Electrocatalytic oxidation of cyclohexene was performed in proton-exchange membrane (PEM) and anion-exchange membrane (AEM) electrolyzers. For the efficient electrocatalytic oxidation, the anode catalyst material, applied potential, and solvent used were optimized. In addition, the differences in reactivity between the PEM and AEM electrolyzers were clarified and a mechanism for the oxidation of cyclohexene in each electrolyzer was proposed.