Rigid macroporous poly(divinylbenzene) monoliths with a well-defined bicontinuous morphology prepared by living radical polymerization
Rigid macroporous poly(divinylbenzene) monoliths with a well-defined bicontinuous morphology prepared by living radical polymerization
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DOI：
10.1002/adma.200601026
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发表时间：
2006-09-18
影响因子：
29.4
通讯作者：
Hanada, Teiichi
中科院分区：
文献类型：
--
作者：
Kanamori, Kazuyoshi;Nakanishi, Kazuki;Hanada, Teiichi
使用活性自由基聚合和聚合物相分离器合成具有良好机械和热稳定性并具有明确的双连续结构（见图）的刚性大孔聚（二乙烯基苯）整料。可以通过改变混合物的起始组成来独立地调节大孔尺寸和体积。比例尺代表20 μ m，a-d显示聚二甲基硅氧烷浓度增加
Rigid macroporous poly(divinylbenzene) monoliths with good mechanical and thermal stability and possessing a well-defined bicontinuous structure (see figure) are synthesized using living radical polymerization and a polymeric phase separator. The macropore size and volume can be independently tuned by varying the starting compositions of the mixtures. Scale bars represent 20 m, a-d show increasing polydimethylsiloxane concentration