Products of the reaction of 9-nickelafluorenyllithium complexes with water
Products of the reaction of 9-nickelafluorenyllithium complexes with water
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DOI：
10.1021/om800329u
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发表时间：
2008-07-28
期刊：
影响因子：
2.8
通讯作者：
Sadlo, Jaroslaw
中科院分区：
文献类型：
--
作者：
Buchalski, Piotr;Jadach, Patryk;Sadlo, Jaroslaw
研究了9-茂镍基锂配合物与水的反应。通过镍原子对芳香族C-H键的活化，形成了含芳烃配体的镍镍簇合物，其晶体结构和分子结构由单晶X射线分析确定。
Reactions of 9-nickelafluorenyllithium complexes with water were carried out. Trinickel clusters with aryne ligands were formed (via aromatic C-H bond activation by a nickel atom), whose crystal and molecular structures were determined by single-crystal X-ray analysis.